Glen,
This is a shot in the dark here, but your OS may have an issue handling XML files for some reason. Try the steps on the technical solution at http://usa.autodesk.com/getdoc/id=TS1053833.
I had a case where a user had the same issue and I could not reproduce the problem unless I renamed the ASHRAE.xml file. They never told me if my recommendation worked so I'm not sure if the above will do it. I know that the process won't hurt though.
Let me know if this takes care of the problem.
Cheers,
Kyle B
Autodesk Product Support
Kyle Bernhardt
Director
Building Design Strategy
Autodesk, Inc.