An excellent example is located at the linked blog.
http://blog.ads-sol.com/2014/08/save-as-pdf-dwf-ilogic.html
Also, there is an example in the help, but it doesn't seem to explain very well how to save all sheets to a single file. The example linked above does a great job.
Code example from the ads-sol blog.
' Testing code excerpt from...
' http://blog.ads-sol.com/2014/08/save-As-pdf-dwf-ilogic.html
dir5 = "c:\temp"
oFileName = "testing"
'------------------- Complex code added to save all sheets ----------------
oPDFAddIn = ThisApplication.ApplicationAddIns.ItemById _
("{0AC6FD96-2F4D-42CE-8BE0-8AEA580399E4}")
oDWFAddIn = ThisApplication.ApplicationAddIns.ItemById _
("{0AC6FD95-2F4D-42CE-8BE0-8AEA580399E4}")
oDocument = ThisApplication.ActiveDocument
oContext = ThisApplication.TransientObjects.CreateTranslationContext
oContext.Type = IOMechanismEnum.kFileBrowseIOMechanism
oOptions = ThisApplication.TransientObjects.CreateNameValueMap
oDataMedium = ThisApplication.TransientObjects.CreateDataMedium
If oPDFAddIn.HasSaveCopyAsOptions(oDataMedium, oContext, oOptions) Then
oOptions.Value("All_Color_AS_Black") = 1
oOptions.Value("Remove_Line_Weights") = 1
oOptions.Value("Vector_Resolution") = 400
'this publish all doens't work
oOptions.Value("Sheet_Range") = Inventor.PrintRangeEnum.kPrintAllSheets
'try a different publish all command
'oOptions.Value("Publish_All_Sheets") = 1
'oOptions.Value("Custom_Begin_Sheet") = 2
'oOptions.Value("Custom_End_Sheet") = 4
End If
'Set the PDF target file name
oDataMedium.FileName = dir5 & "\" & oFileName & "_Rev" & oRevNum & ".pdf"
'Publish document
oPDFAddIn.SaveCopyAs(oDocument, oContext, oOptions, oDataMedium)
i = MessageBox.Show("View the PDF file?", "Title",MessageBoxButtons.YesNo)
If i = vbYes Then : launchviewer = 1 : Else : launchviewer = 0 : End If
If launchviewer = 1 Then ThisDoc.Launch(oDataMedium.FileName)
' Done for now.
M.