@jonniepickering wrote:
I have a 3D scan .stl
I simply wish to create aero parts that can fit snuggly onto the surfaces that have been scanned.
Once I have built the model in Fusion, I will then have these CNC'd or 3D printed and a mould taken.
Aha! I had a feeling that is what you want to do but wasn't sure.
You made a statement in your initial post I don't fully understand :
"the back edge should be fully curved and the front edges that attach to the existing wing should just curve down to the surface (90 deg)"
I am assuming that means that you want the surfaces in the area lined in red to blend perfectly smoothly and also for the rear edge of the existing spoiler to transition smoothly into the rear edge of the extension as I try to indicate with the green line.

From a modeling standpoint that can be done albeit isn't necessarily simple.
However, from a manufacturing standpoint, in order to blend perfectly between surfaces that will require some application of Bondo, sanding, and re-painting. When you 3D print this, or CNC machine this you'll end up with some minimal material thickness. Also when gluing this onto the existing piece you'll have to assume some bond gap to be taken by the adhesive. That will result in some form of a lip.
Can you explain what your expectations are in terms of the finished end product and what you had planned in terms of attaching the 3D printed or CNC machined piece to the existing part?
The reason I am asking this is that we can, of course, try to create perfect blends in CAD, but in the end but might end up spending time on perfecting CAD geometry that you won't be able to exactly replicate with retrofit manufacturing methods.
As such, the T-Spline geometry you have in the model might serve as a good start.