The problem with the non-union of materials is that the concrete wall and the floor and structural foundation are different, so the join leaves a line that represents this difference in materials, the other point is about the structural foundation, just change the order between the structural foundation of the floor.
Another point I saw is that the floor is not touching the structural wall.
I made a video changing the materials, using the Switch Join Order and connecting floor to the wall.
https://autode.sk/3ocWaUo
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Mauricio Santos Filho Arquiteto | BIM Manager