Most likely those libpng warnings are for some png textures you're using. See https://wiki.archlinux.org/index.php/Libpng_errors
But since the render will be using tx files (unless you disabled the auto tx conversion), those warnings are probably coming from the maketx stage, which is pre-render. So probably safe to ignore the warnings.
For the slow render, let's see an Arnold log (verbosity level Warnings + Info). For one thing, the log header will have your system info, like this:
00:00:00 1496MB | log started Thu May 18 16:52:41 2017
00:00:00 1496MB | Arnold 5.0.0.2 [f2591180] windows icc-17.0.2 oiio-1.7.12 osl-1.8.2 vdb-4.0.0 rlm-12.2.2 2017/05/08 11:52:26
00:00:00 1496MB | host application: MtoA 2.0.0.1 7493eb5a (master) Maya 2017
00:00:00 1496MB | running on REMFDXQFB2, pid=10100
00:00:00 1496MB | 2 x Intel(R) Xeon(R) CPU E5-2650 v3 @ 2.30GHz (20 cores, 40 logical) with 32690MB
00:00:00 1496MB | Windows 7 Enterprise Edition Service Pack 1 (version 6.1, build 7601)
00:00:00 1496MB | soft limit for open files raised from 2048 to 2048
// Stephen Blair
// Arnold Renderer Support