Having managed, created, and ran Autodesk Deployments for many years, indeed, it was ran as an Admin. No mistake here. The message in the dialog box was only poorly written error capturing on Autodesk's part.
As described in the solution that worked, all I did was to modify the batch to run the local Installer instead of the one found in the deployment at "\\DeployServ\cad\deploy\2024\Revit_2\image\Installer.exe".
Additionally, I made certain the local installer was the latest version. (Autodesk Access Version 1.43.0.186)
This is what worked, no change in the permissions was made.
Interestingly, the error at the outset "UNC paths are not supported, Defaulting to Windows directory." remained... as the path to the Collect.xml was still used ("\\DeployServ\cad\deploy\2024\Revit_2\image\Collect.xml")
I would like to get some clarification from Autodesk on this issue as to why all previous deployments worked and this one initially did not.