Hi,
AFAIK it is not possible... and it is pointless.
If You want to use thicker column flange, just use custom welded I section with the same web height and use it as column profile (only in connection design).
The only problem is, that You can use only symmetrical I sections.
You can use I-section with thicker flanges in the model in knee area, but it is not necessary - You can use it only in Connection Design module:
Jerzy
Some additional comments to Knee connection design:
Jerzy