When exporting to DWG from Revit, Revit reads the default plot style from AutoCAD so it's VERY hidden and not intuitive by any means. If you need to adjust the default you can do the following.
In AutoCAD:
-Navigate to File --> Options then Plot and Publish in Autocad
-Set the Default Output Device to "DWG to PDF"
-Select Add or Configure Plotters
-Select "DWG to PDF" from the list.
-This opens the Plotter Configuration Editor. Change the paper size in Device and Document Settings.
-Once you've done that export from Revit. If multiple people are working on the export process, each user will have to do this on their computer.
Note that Revit automatically sets the Plot Scale in the resulting DWG file Page Setup for the Layout to be 'Fit to Paper'. So if you have any content in Revit that is hanging off the page (visible or not, like Crop Boundaries) then it will affect the Plot Scale in the DWG file. To fix that you have to open up the Page Setup in AutoCAD change the Plot Scale to 1 : 1. See attached image. This is very tedious if you need to do a lot of sheets.
-Andy Brack