The error message says that this DLL is not a valid .NET assembly.
That is very probably correct.
Why are you trying to reference this DLL?
You probably should not.
I think all the assemblies that can possibly be of interest to you and your add-in are named RevitAPI*.dll:
C:\Program Files\Autodesk\Revit 2021>dir RevitAPI*dll
Directory of C:\Program Files\Autodesk\Revit 2021
07/09/2020 09:43 AM 27,231,120 RevitAPI.dll
07/09/2020 03:44 PM 80,272 RevitAPIBrowserUtils.dll
07/09/2020 03:42 PM 973,200 RevitAPIFoundation.dll
07/09/2020 03:43 PM 371,088 RevitAPIIFC.dll
07/09/2020 03:43 PM 31,120 RevitAPILink.dll
07/09/2020 03:44 PM 103,312 RevitAPIMacros.dll
07/09/2020 03:43 PM 540,048 RevitAPIMacrosInterop.dll
07/09/2020 03:44 PM 545,168 RevitAPIMacrosInteropAPI.dll
07/09/2020 03:43 PM 242,064 RevitAPISteel.dll
07/09/2020 03:44 PM 2,517,904 RevitAPIUI.dll
07/09/2020 03:44 PM 62,864 RevitAPIUILink.dll
07/09/2020 03:44 PM 83,344 RevitAPIUIMacros.dll
07/09/2020 03:44 PM 253,328 RevitAPIUIMacrosInterop.dll
07/09/2020 03:44 PM 452,496 RevitAPIUIMacrosInteropAPI.dll
14 File(s) 33,487,328 bytes