Hi Michael,
as far as I can see, there is still no such Material Library API.
So we still have an image file name but not the file path.
There may be a workaround, just an idea:
The file is stored using "Autodesk Material Library 201x".
One could browse the Windows Registry to get the related directories of this program.
Once found the paths, one could examine the readable files (*.txt, *xml, etc.) existing there, to gain further information.
Just searching for "sample.png", inside those files.
I don't believe that a "sample.png" file can be found directly since there may be some sort of mapping, e.g. it may be saved as "previews/12345.png".
Perhaps this mapping information can be found out.
Just a guess.
Perhaps somebody may pick up this idea and spend some time to try it out...
Revitalizer