Hi Mike,
This is not very difficult to achieve. I have made a layer stackup preset for you named: Mike.Durian.CustomStack.estackup.zip (you need to un-zip it before using). You can load the preset by using the layer stackups drop-down box to teh left of the Layer Stack dialog, please see pictures below:



After loading the layer stack preset following the steps shown in the 3 pictures above you can update the layer stack as required by using the Right Mouse Button context menu that allows you to add / delete layers including Silk Screen, Solder Mask, Surface Finish, Pre-Preg. etc. You can also change layer material properties by toggling on the "Edit material properties" check-box:

If you make changes you can save them by using the Save button to the right of the Layer Stack preset drop-down box, please see picture below:

The easiest way to start customizing a layer stack is by starting with one of the provided presets that you can pick from the drop-down box. When you start a new design that will have 2 signal layers the "2 Layer Stack" will be selected. You can change to any of the existing simetrical setups for 2, 4, 6,.., 16 layers adn then customize to make it your own.
The other way is to use one of the Eagle layer setups, for your setup is this: ([2:1+(2*15)+16:15]). You can load it by selecting the "Open From Setup String..." command as shown below:

In the subsequent dialog:

Insert you layer setup string click Apply and the layer stack will be populated with the right setup. Then you can adjsut it using the Right Mouse Click context menu commands:

and if you want to change layer material properties locally then check the Edit material properties check-box and the layer stack grid cells will become editable.
I hope this will help you.
Please let me know if you need anything else.
Kind regards,
Constantin Popescu
Constantin Popescu
Principal Software Engineer