I haven't set up a simulation in this way exactly, but I would start with the following.
It sounds like you already know what the exhaust cfm and temperature is due to testing or some educated estimate. I would set up your car in a wind tunnel type of air volume. For instance if the car is traveling from right to left, the left inlet of the air volume has boundary conditions of ambient temp and 100 mph (speed of the car). Right outlet surface of the air volume has pressure = 0. This is very similar to the tutorial example.
The exhaust part is a bit trickier. Since it sounds like you don't need to solve for the internal air flow of the engine and exhaust I would simplify it by putting a cfm boundary condition on the air intake of the car and a cfm condition and temperature boundary condition on the exhaust. If you know the air speed and cross section area of the exhaust you could calculate cfm. You may also need a good geometry representation of the air inlet and exhaust to help direct the airflow depending on how critical you need to be of the results.
In this set up there isn't a second air volume. You are treating the car as a black box that you don't know what is happening on the inside. You would be forcing the mass balance in the car manually by your boundary conditions. Normally this is a bad practice as your simulation needs the freedom to have very small mass balance errors due to the nature of FEA. I think you can do this here because you are allowing he entire system to still solve with these errors on the outlet p=0 side of the wind tunnel.