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As far as I know there is not a real difference. When you place a structural wall, some default values are set differenlty between architectural and structural. For example a Structural Wall has the "Structural" Parameter selected while the architectural has not. Also the placement is little bit different Structural elements tend to be placed from below the placement work plane up to the workplane while architectural element tend to be from placement workplane upwards.
After placement you can convert structural wall into architectural wall and vice versa.
Louis
Please mention Revit version, especially when uploading Revit files.
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