OK,
First, place the bolt into the assembly. In the browser, click on the "Constraint" icon. The fourth box shows a yellow bolt profile in a blue block. Click that. Pass the pointer over the bolt, and highlight the circle where the body of the bolt joins the head. The "2" buttion should then be active, so find the hole you want the bolt to fit, and highlight it. Be careful that you get the outermost circle on the surface, or you will end up with the bolt embedded inside the part. Click there, and you should get a preview. If you like it, click Apply. That should do it.
Tom