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Do you know if there is an adskflex.opt options file that is preventing license borrowing from happening?
If you want to PM me your debug.log file from your license manager, I will take a look at it for you.
I recently encountered a similar problem, however, I am able to borrow a license for up to 161 days, and can't borrow for the maximum period. If I select the maximum period of 180 days, as limited by the product, i get the same [-5.414.0] Error.
I am using both Infrastructure and Prduct Design Suite Ultimate, running Windows 8.1
Hopefully you can help with this.